论文标题
压缩AUF3中顺式桥梁的意外持续存在
Unexpected persistence of cis-bridged chains in compressed AuF3
论文作者
论文摘要
拉曼散射测量结果表明，即使在45 GPA的压缩下，也保留在AUF3中的顺式桥梁 - 与Meta-GGA计算相反，这表明具有这种基序的结构在4 GPA以上是热力学上不稳定的结构。这种亚抗性表明，在低压下，新型的金氟化物（例如AUF2）可能比以前提出的低。
Raman scattering measurements indicate that cis-bridged chains are retained in AuF3 even at a compression of 45 GPa - in contrast to meta-GGA calculations suggesting that structures with such motifs are thermodynamically unstable above 4 GPa. This metastability implies that novel gold fluorides (e.g. AuF2) might be attainable at lower pressures than previously proposed.
