论文标题

扭曲弯曲列表:一个错误的身份案例

The Twist Bend Nematic: A Case of Mistaken Identity

论文作者

Samulski, Edward T., Vanakaras, Alexandros G., Photinos, Demetri J.

论文摘要

我们回顾了迈耶(Meyer)在nematics的弗兰克·森(Frank-Oseen)弹性理论中如何共同构思迈耶(Mayer)如何建立宏观尺度的扭曲和弯曲的猜想,以创建单轴,一次性nematory导演的灵活安排,即所谓的“扭曲弯曲弯曲nematic nematic nematic nematic nematic” $ \ rm n_ n_ n_ {tb} $。我们表明,自2011年以来,在Toriumi发现并称为$ \ rm n_x $的奇数甲基链苯基二聚体中观察到的第二个,温度较低的列中相,已被错误地识别为$ \ rm n_ {tb} $。此外,随着出现了$ \ rm n_x $的更多定量数据,迈耶的简单预测已被扭曲以适应这些发现。实际上,$ \ rm n_x $中的分子组织符合$ \ rm n_ {pt} $相位,这是2016年提出的非线性中质量的极性,扭曲的非线性中的排列。$ \ rm n_ {pt} $的属性从$ n_ {pt} $中得到了总结和区分。 $ \ rm n_x $相位,同样重要的是,要鼓励研究人员继续寻找表现出Meyer开创性的理论建议的液晶,即,由Achiral Molecules组成的简单神秘物质可以存在。

We review the physics underlying Meyer's conjecture of how macroscopic-scale twist and bend conspire within the Frank-Oseen elasticity theory of nematics to create a heliconical arrangement of the uniaxial, apolar nematic director, the so-called "twist bend nematic" $\rm N_{TB}$. We show that since 2011 a second, lower-temperature nematic phase observed in odd methylene-linked cyanobiphenyl dimers discovered by Toriumi and called $\rm N_X$, has been incorrectly identified as $\rm N_{TB}$. Moreover, as more quantitative data on the $\rm N_X$ emerged, Meyer's simple prediction has been distorted to accommodate those findings. In fact, the molecular organization in the $\rm N_X$ conforms to the $\rm N_{PT}$ phase, a polar, twisted arrangement of nonlinear mesogens advanced in 2016. The attributes of the $\rm N_{PT}$ are summarized and differentiated from those of the $\rm N_{TB}$ in an effort to contribute to a better understanding of the $\rm N_X$ phase and, equally important, to encourage researchers to continue to search for a liquid crystal that exhibits Meyer's pioneering theoretical suggestion, namely that form-chirality can exist in simple nematics composed of achiral molecules.

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