论文标题
通过施加的电解质的横流抑制电盲物和形态不稳定性
Suppression of Electroconvective and Morphological Instabilities by an Imposed Cross Flow of the Electrolyte
论文作者
论文摘要
在许多应用中,包括电透析,电池和燃料电池在内的许多应用中,电染色及其与形态不稳定性的耦合很重要。在这项工作中,我们使用两种方法研究了二维通道流对电向和形态不稳定性的影响。在批量分析中,我们考虑了由第二种电磁速度速度边界条件驱动的电自动物区域的不稳定性,并为小波数和大型波数提供了渐近溶液。在完整的分析中,我们考虑液体电解质的整个区域,并使用超球光谱方法来解决特征值问题。两项研究都表明,施加的流动显着影响电向感染的不稳定性。施加的流通过变形了扰动的离子浓度场,并阻止从低浓度区域转移到高浓度区域,从而产生屏蔽效果,从而阻碍离子转移。它完全抑制了小波数的电向不稳定性,并降低了大型波数扰动的生长速度。流动对形态不稳定性的直接影响很小,而抑制电位感染不稳定性可能会改变耦合不稳定性最不稳定模式的波数。对于电向感染的不稳定性,大量分析在质量上与高波数的完整分析在质上不同。对于形态的不稳定,在小波数和大型波数的两项研究之间都发现了良好的一致性。
Electroconvection and its coupling with a morphological instability are important in many applications, including electrodialysis, batteries and fuel cells. In this work, we study the effects of a two-dimensional channel flow on the electroconvective and morphological instabilities using two approaches. In the bulk analysis, we consider the instability of the electroneutral bulk region driven by a second kind electroosmosis slip velocity boundary condition and derive the asymptotic solutions for small and large wavenumbers. In the full analysis, we consider the entire region of the liquid electrolyte and use the ultraspherical spectral method to numerically solve the eigenvalue problems. Both studies show that the imposed flow significantly affects the electroconvective instability. The imposed flow generates a shielding effect by deforming the perturbed ion concentration field and hinders the ion transfer from low- to high- concentration regions which causes the instability. It fully suppresses the electroconvective instability at small wavenumbers and reduces the growth rate of the perturbations at large wavenumbers. The direct effect of the flow on the morphological instability is minor, while the suppression of the electroconvective instability may change the wavenumber of the most unstable mode of the coupled instabilities. For the electroconvective instability, the bulk analysis is qualitatively different from the full analysis at high wavenumbers. For the morphological instability, good agreement is found between the two studies at both small and large wavenumbers.