论文标题

严重的塑性变形对无形PD玻璃和过冷的液态的放松的影响

Impact of severe plastic deformation on the relaxation of glassy and supercooled liquid states of amorphous Pd$_{40}$Ni$_{40}$P$_{20}$

论文作者

Hassanpour, Afrouz, Hilke, Sven, Rösner, Harald, Divinski, Sergiy V., Wilde, Gerhard

论文摘要

通过高压扭转对PD $ _ {40} $ ni $ _ {40} $ p $ _ {20} $的玻璃状和过冷的液态的放松的严重塑性变形对放松的影响,使用了差异扫描量表的组合进行了研究。分析了由于变形而引起的量热信号的变化,并分析了随后的热处理,并发现了相对于中距离(MRO)的变形(恢复)和退火(弛豫)之间的相关性(RESEWERYATION)。此外,确定了超冷液态放热峰的发生与MRO类型的特定变化之间的耦合。这些发现是在潜在能源景观方案中理解的,该方案为MRO工程提供了新方法。

The impact of severe plastic deformation by high-pressure torsion on the relaxation of the glassy and supercooled liquid states of Pd$_{40}$Ni$_{40}$P$_{20}$ was investigated using a combination of differential scanning calorimetry, low-temperature heat capacity and fluctuation electron microscopy. The changes in the calorimetric signals due to deformation and subsequent heat treatments were analyzed and a correlation between deformation (rejuvenation) and annealing (relaxation) was found in relation to medium-range order (MRO). Moreover, a coupling between the occurrence of an exothermic peak in the supercooled liquid state and specific changes in the MRO types were identified. These findings are comprehended in a potential energy landscape scheme offering a new approach for MRO engineering of glasses.

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