论文标题

理查森·戈丁(Richardson-Gaudin

Richardson-Gaudin geminal wavefunctions in a Slater determinant basis

论文作者

Fecteau, Charles-Émile, Berthiaume, Frédéric, Khalfoun, Meriem, Johnson, Paul Andrew

论文摘要

Geminal波函数已被用于建模强相关的电子。这些波函数代表了弱相关的电子对的产物,合理的近似值可计算,而多项式成本。特别是,理查森·戈丁州最近被用作变异的安萨兹。这项贡献旨在用量子化学的传统语言来解释理查森 - 戈丁波函数。

Geminal wavefunctions have been employed to model strongly-correlated electrons. These wavefunctions represent products of weakly-correlated pairs of electrons and reasonable approximations are computable with polynomial cost. In particular, Richardson-Gaudin states have recently been employed as a variational ansatz. This contribution serves to explain the Richardson-Gaudin wavefunctions in the conventional language of quantum chemistry.

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