论文标题

各向异性2D半导体中强烈结合的激子和Trions

Strongly-bound excitons and trions in anisotropic 2D semiconductors

论文作者

Yoon, Sangho, Kim, Taeho, Seo, Seung-Young, Shin, Seung-Hyun, Song, Su-Beom, Kim, B. J., Watanabe, Kenji, Taniguchi, Takashi, Lee, Gil-Ho, Jo, Moon-Ho, Qiu, Diana Y., Kim, Jonghwan

论文摘要

单层和少量磷酸是各向异性准二维(Quasi-2d)van der waals(vdw)半导体,具有线性二基化的光 - 一种相互作用,并且在红外频率中具有广泛可低调的直接带隙。尽管最近对具有独特特性的强型激子的理论预测,但由于装置制造过程中严重的氧化,探测激子准粒子的实验挑战。在这项研究中,我们报告了内在双层磷的强烈结合激子和具有高肛门性光学特性的TRION的观察,这些特性通过六角形硝化硼(HBN)封装,在田间效应的跨晶体管(FET)的几何形状中通过封装,可以保护它们免受氧化的影响。反射对比度和光致发光光谱清楚地揭示了来自各向异性激子和HBN已封装的双层磷酸中的Trions的线性双色体光谱。激子Rydberg系列的光学共振表明,即使使用HBN进行介电筛选,中性激子结合能也超过100 MeV。游离孔的静电注射可从电荷中性系统的光学带隙以下〜30 meV的正trion(带电激子)的其他光学共振。我们的工作显示了单层和几层磷烯的激动人心的可能性,作为基于具有两倍各向异性的强结合激子探索多体物理学以及新颖的光子学和光电子的平台。

Monolayer and few-layer phosphorene are anisotropic quasi-two-dimensional (quasi-2D) van der Waals (vdW) semiconductors with a linear-dichroic light-matter interaction and a widely-tunable direct-band gap in the infrared frequency range. Despite recent theoretical predictions of strongly-bound excitons with unique properties, it remains experimentally challenging to probe the excitonic quasiparticles due to the severe oxidation during device fabrication. In this study, we report observation of strongly-bound excitons and trions with highly-anisotropic optical properties in intrinsic bilayer phosphorene, which are protected from oxidation by encapsulation with hexagonal boron nitride (hBN), in a field-effect transistor (FET) geometry. Reflection contrast and photoluminescence spectroscopy clearly reveal the linear-dichroic optical spectra from anisotropic excitons and trions in the hBN-encapsulated bilayer phosphorene. The optical resonances from the exciton Rydberg series indicate that the neutral exciton binding energy is over 100 meV even with the dielectric screening from hBN. The electrostatic injection of free holes enables an additional optical resonance from a positive trion (charged exciton) ~ 30 meV below the optical bandgap of the charge-neutral system. Our work shows exciting possibilities for monolayer and few-layer phosphorene as a platform to explore many-body physics and novel photonics and optoelectronics based on strongly-bound excitons with two-fold anisotropy.

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