论文标题
柜台的强耦合理论与对称充电墙之间的硬芯
Strong-coupling theory of counterions with hard cores between symmetrically charged walls
论文作者
论文摘要
通过蒙特卡洛模拟和分析计算的组合,我们研究了高电荷平面界面之间的有效相互作用,该界面被移动柜台(无盐系统)中和。尽管大多数先前的分析都集中在类似点状的反面上,但我们将其视为带电的硬球。因此,当空间效应在起作用时,我们就会解决类似吸引力的命运。分析方法分配了两个子人群中的反面,一个用于每个板,并整合了一个子群,以得出其余的一个有效的哈密顿量。有效的汉密尔顿具有四粒子相互作用的斑块,并且通过计算吉布斯 - 贝格利博夫的自由能不等式来解决。治疗的根源是,在强静电耦合下,电荷系统形成有序的安排,可能会受到空间相互作用的影响。围绕参考位置的波动被解释。在高耦合处的主导顺序中,发现空间效应不会显着影响板间的有效压力,而在硬球重叠的小距离处则是不可避免的,因此排除了配置。
By a combination of Monte Carlo simulations and analytical calculations, we investigate the effective interactions between highly charged planar interfaces, neutralized by mobile counterions (salt-free system). While most previous analysis have focused on point-like counterions, we treat them as charged hard spheres. We thus work out the fate of like-charge attraction when steric effects are at work. The analytical approach partitions counterions in two sub-populations, one for each plate, and integrates out one sub-population to derive an effective Hamiltonian for the remaining one. The effective Hamiltonian features plaquette four-particle interactions, and it is worked out by computing a Gibbs-Bogoliubov inequality for the free energy. At the root of the treatment is the fact that under strong electrostatic coupling, the system of charges forms an ordered arrangement, that can be affected by steric interactions. Fluctuations around the reference positions are accounted for. To dominant order at high coupling, it is found that steric effects do not significantly affect the interplate effective pressure, apart at small distances where hard sphere overlap are unavoidable, and thus rule out configurations.