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Stellar evolution models calculate convective boundaries using either the Schwarzschild or Ledoux criterion, but confusion remains regarding which criterion to use. Here we present a 3D hydrodynamical simulation of a convection zone and adjacent radiative zone, including both thermal and compositional buoyancy forces. As expected, regions which are unstable according to the Ledoux criterion are convective. Initially, the radiative zone adjacent to the convection zone is Schwarzschild-unstable but Ledoux-stable due to a composition gradient. Over many convective overturn timescales the convection zone grows via entrainment. The convection zone saturates at the size originally predicted by the Schwarzschild criterion, although in this final state the Schwarzschild and Ledoux criteria agree. Therefore, the Schwarzschild criterion should be used to determine the size of stellar convection zones, except possibly during short-lived evolutionary stages in which entrainment persists.