论文标题

通过高$κ$介电层自封离子门控NBN超薄膜中超导性的可逆调整

Reversible Tuning of Superconductivity in Ion-Gated NbN Ultrathin Films by Self-Encapsulation with a High-$κ$ Dielectric Layer

论文作者

Piatti, Erik, Colangelo, Marco, Bartoli, Mattia, Medeiros, Owen, Gonnelli, Renato S., Berggren, Karl K., Daghero, Dario

论文摘要

离子门控是一种强大的技术,用于通过电场引起的电荷掺杂来调整材料的物理特性,但很容易在纯静电范围以外的封闭材料中引入外部障碍和不希望的电化学修饰。相反,可逆,挥发性和静电调制在通过离子门具有可实现的超高诱导的电荷密度实现的新型设备概念的可靠设计和操作中至关重要。在这里,我们证明了一种简单有效的方法,可以通过对其表面的控制氧化来实现表面敏感的超薄氮化物膜的可逆和挥发性门控。所得的氧化物封装层表现出与未封装的离子晶体管相当的电容,可承受栅极电解质的电化学稳定性窗口以外的栅极电压,并启用了封闭胶片的正常态电阻率和超管过渡温度的完全可逆的可调性。我们的方法应该可以转移到其他标准封装技术不容易适用的材料和设备几何形状上。

Ionic gating is a powerful technique for tuning the physical properties of a material via electric field-induced charge doping, but is prone to introduce extrinsic disorder and undesired electrochemical modifications in the gated material beyond pure electrostatics. Conversely, reversible, volatile and electrostatic modulation is pivotal in the reliable design and operation of novel device concepts enabled by the ultrahigh induced charge densities attainable via ionic gating. Here we demonstrate a simple and effective method to achieve reversible and volatile gating of surface-sensitive ultrathin niobium nitride films via controlled oxidation of their surface. The resulting niobium oxide encapsulation layer exhibits a capacitance comparable to that of non-encapsulated ionic transistors, withstands gate voltages beyond the electrochemical stability window of the gate electrolyte, and enables a fully-reversible tunability of both the normal-state resistivity and the superconducting transition temperature of the encapsulated films. Our approach should be transferable to other materials and device geometries where more standard encapsulation techniques are not readily applicable.

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