论文标题
电化学和最大反应速率的平衡
Equilibria in Electrochemistry and Maximal Rates of Reaction
论文作者
论文摘要
我们考虑Gibbs对化学平衡的定义，并将其与动态平衡联系起来，而没有形成的物质。我们确定活性系数是温度和压力的函数，在有或没有溶剂相互作用的反应中，在必要时纳入了Raoult定律和亨利定律中的误差项。我们使用Nernst方程计算最大反应路径，并将结果应用于电化学。
We consider Gibbs' definition of chemical equilibrium and connect it with dynamic equilibrium, in terms of no substance formed. We determine the activity coefficient as a function of temperature and pressure, in reactions with or without interaction of a solvent, incorporating the error terms from Raoult's Law and Henry's Law, if necessary. We compute the maximal reaction paths and apply the results to electrochemistry, using the Nernst equation.
