论文标题

金属中非热电子能量分布的激发和放松,并施加到黄金

Excitation and Relaxation of Nonthermal Electron Energy Distributions in Metals with Application to Gold

论文作者

Riffe, D. M., Wilson, Richard B.

论文摘要

储层计算是预测湍流的有力工具,其简单的架构具有处理大型系统的计算效率。然而,其实现通常需要完整的状态向量测量和系统非线性知识。我们使用非线性投影函数将系统测量扩展到高维空间,然后将其输入到储层中以获得预测。我们展示了这种储层计算网络在时空混沌系统上的应用,该系统模拟了湍流的若干特征。我们表明,使用径向基函数作为非线性投影器,即使只有部分观测并且不知道控制方程,也能稳健地捕捉复杂的系统非线性。最后,我们表明,当测量稀疏、不完整且带有噪声,甚至控制方程变得不准确时,我们的网络仍然可以产生相当准确的预测,从而为实际湍流系统的无模型预测铺平了道路。

A semiempirical theory for the excitation and subsequent relaxation of nonthermal electrons is described. The theory, which is applicable to ultrafast-laser excited metals, is based on the Boltzmann transport equation for the carrier distribution function $f(ε,t)$ and includes electron-phonon, electron-electron, and electron-photon scattering integrals in forms that explicitly depend on the electronic density of states. Electron-phonon coupling is treated by extending the theory of Allen [Phys. Rev. Lett. 59, 1460 (1987)] to include highly-excited nonthermal electron distributions, and is used to determine the energy transfer rate between a nonthermal electron subsystem and a thermal phonon subsystem. Electron-electron scattering is treated with a simple energy-conserving electron-electron scattering integral. The electron-photon integral assumes photon absorption is phonon assisted. We apply the theory to analyze prior ultrafast thermionic emission, two-color photoemission, and electronic inelastic light (Raman) scattering experiments on Au. These analyses show that getting the details of $f(ε,t)$ is necessary for proper interpretation of each experiment. Together, the photoemission and Raman-scattering analyses indicate an electron excited 1 eV above the Fermi level has an electron-electron scattering time in the range of 25 to 55 fs.

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